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- W2051289683 abstract "A unique 1,2-acyl migration for the construction of quaternary carbon in a one-pot reaction under visible light is described. By irradiating a platinum(II) polypyridyl complex with visible light, enamine 1 is able to react with alcohol 2 to yield compound 3 featuring a quaternary carbon via 1,2-acyl migration and concurrent esterification. Studies on the mechanism reveal that the platinum(II) complex is able to generate singlet oxygen (1O2) that is responsible for this unprecedented intramolecular 1,2-acyl migration transformation." @default.
- W2051289683 created "2016-06-24" @default.
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- W2051289683 date "2014-11-03" @default.
- W2051289683 modified "2023-10-18" @default.
- W2051289683 title "A Unique 1,2-Acyl Migration for the Construction of Quaternary Carbon by Visible Light Irradiation of Platinum(II) Polypyridyl Complex and Molecular Oxygen" @default.
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- W2051289683 doi "https://doi.org/10.1021/ol502995h" @default.
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