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- W2051290029 abstract "The ground-state wave functions of He i and ${mathrm{H}}^{ensuremath{-}}$ have been represented by the superposition of symmetrized analytic central field wave functions for the configurations $1{s}^{2}$, $1s2s$, $1s3s$, $2{p}^{2}$, $2p3p$, $3{d}^{2}$, and $4{f}^{2}$. The radial functions were taken to be the product of an exponential and a polynomial. The coefficients in the polynomials were chosen to insure the orthogonality of the one-electron wave functions. The parameters in the exponentials and the coefficients in the linear combinations of the wave functions for the different configurations were chosen so that the ground-state function gave the minimum energy. The resulting energies for He i and ${mathrm{H}}^{ensuremath{-}}$ are -5.79830 and -1.05190 respectively in units of the Rydberg for the corresponding atom. These results together with others are discussed." @default.
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- W2051290029 date "1956-12-15" @default.
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- W2051290029 title "Ground-State Wave Functions for He i and<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=normal>H</mml:mi></mml:mrow><mml:mrow><mml:mo>−</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>Obtained by the Superposition of Central Field Functions" @default.
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- W2051290029 doi "https://doi.org/10.1103/physrev.104.1593" @default.
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