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- W2051290758 abstract "CuCl microcrystals with different morphologies such as tetrahedra, etched tetrahedra, tripod dendrites, and tetrapods were synthesized using CuCl2⋅2H2O as the copper precursor in the mixed solvent of acetylacetone and ethylene glycol. The samples were characterized with X-ray diffraction, scanning electron microscopy, infrared spectroscopy, and transmission electron microscope. Cu(C5H7O2)2 was identified as the key intermediate, and the morphology and structure of the CuCl microcrystals were highly dependent on the reaction time and temperature, as well as the volume of the solvents. The catalytic properties of these CuCl microcrystals were explored in the dimethyldichlorosilane synthesis via Rochow reaction. Compared to the commercial CuCl microparticles with irregular morphology and dense internal structure, the obtained CuCl microcrystals possessed regular morphology and different exposed crystal planes and showed much higher dimethyldichlorosilane selectivity and Si conversion via the Rochow reaction because of the enhanced formation of active CuxSi phase and gas transportation within the dendritic structure, demonstrating the significance of regular morphology of the copper-based catalysts in catalytic organosilane synthesis." @default.
- W2051290758 created "2016-06-24" @default.
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- W2051290758 date "2013-08-01" @default.
- W2051290758 modified "2023-10-18" @default.
- W2051290758 title "Solvothermal synthesis of copper (I) chloride microcrystals with different morphologies as copper-based catalysts for dimethyldichlorosilane synthesis" @default.
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- W2051290758 doi "https://doi.org/10.1016/j.jcis.2013.04.028" @default.
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