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- W2051294175 abstract "Softly does it: The title reaction, catalyzed by a AgPF6/(R)-biphep-type ligand/DBU complex, is described (see scheme). This protocol gives efficient access to syn-configured α-sulfanyl-β-hydroxy lactones in a highly enantioselective manner. In one particular case, the sulfide group was stereospecifically replaced with a hydroxy group to afford an enantioenriched tertiary alcohol, which upon further manipulation led to a class of densely functionalized SPT inhibitors. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W2051294175 created "2016-06-24" @default.
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- W2051294175 date "2012-03-13" @default.
- W2051294175 modified "2023-10-02" @default.
- W2051294175 title "A Direct Catalytic Asymmetric Aldol Reaction of α-Sulfanyl Lactones: Efficient Synthesis of SPT Inhibitors" @default.
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- W2051294175 doi "https://doi.org/10.1002/anie.201200520" @default.
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