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- W2051298406 abstract "The combination of $^{16}mathrm{O}$(ensuremath{alpha},ensuremath{alpha}${)}^{16}$O oxygen resonance measurement and transmission electron microscopy (TEM) provides an effective method to study the kinetics of nucleation and growth of the ${mathrm{Cu}}_{2}$O phase during reduction of CuO thin films. The oxygen-loss kinetics in the CuO thin films upon vacuum annealing has been monitored with use of the oxygen resonance at 3.05 MeV. From the oxygen-loss measurement, the volume fraction of transformation of CuO to ${mathrm{Cu}}_{2}$O as a function of time and temperature has been determined. In situ TEM observation measures the growth of ${mathrm{Cu}}_{2}$O grains. When these results were analyzed with the model of phase transformation of Johnson, Mehl, and Avrami, the activation enthalpy of nucleation of the ${mathrm{Cu}}_{2}$O phase in the CuO matrix has been deduced as ensuremath{Delta}${mathit{E}}_{mathit{n}}$=2.3 eV/atom. The specific interfacial energy between the CuO and ${mathrm{Cu}}_{2}$O phases has been estimated to be in the range 0.3--0.85 eV/atom, and the number of atoms in the critical nucleus of ${mathrm{Cu}}_{2}$O has been calculated to be about 23 atoms." @default.
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- W2051298406 title "Nucleation and growth of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Cu</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>O in the reduction of CuO thin films" @default.
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- W2051298406 doi "https://doi.org/10.1103/physrevb.45.5683" @default.
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