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- W2051299048 abstract "Catalytic currents of V(III)-EDTA regenerated by NO3− were observed in polarography under the pseudo-first-order condition. The rate constant k1 evaluated for various combinations of [NO3−] and [V(III)-EDTA] decreased with an increase in (NO3−]/[V(III)-EDTA]. The value of k1 extrapolated to [NO3−]/[V(III)-EDTA] = 0 was 270 mol−1 dm3 s−1. From an analysis of the concentration dependence of k1, the catalytic reaction was associated with decomposition of NO3−. In a solution containing V(IV)-EDTA, the polarograms consisted of two stepwise reduction waves, with the second one giving rise to a catalytic reaction with NO3−. The rate constant k'1 was also evaluated and showed a concentration dependence different from that of k1. It was found that not only decomposition of NO3− but also comproportionation of vanadium EDTA complexes occurred." @default.
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- W2051299048 date "1989-04-01" @default.
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- W2051299048 title "Comparison of the polarographic catalytic currents of V(III)-EDTA/NO3− with those of V(IV)-EDTA/NO3−" @default.
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- W2051299048 doi "https://doi.org/10.1016/0022-0728(89)85001-6" @default.
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