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- W2051306095 abstract "The more the merrier: A multicomponent Sakurai reaction has been developed in which an efficient, highly diastereoselective three-component condensation of an aldehyde 1, allyl silane 2, and silylated alcohol 3 is mediated by trimethylsilyl triflate (TMSOTf). Products such as 4 can serve as direct precursors to dihydropyran skeletons, which is demonstrated by the synthesis of a portion of (+)-ambruticin. TBS=tert-butyldimethylsilyl." @default.
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- W2051306095 date "2006-05-05" @default.
- W2051306095 modified "2023-10-17" @default.
- W2051306095 title "Highly Diastereoselective Silyl-Modified Sakurai Multicomponent Reaction" @default.
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- W2051306095 doi "https://doi.org/10.1002/anie.200600169" @default.
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