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- W2051330232 abstract "Abstract Structural modification of poly(p-phenylene sulphide) (PPS) upon heavy doping with SO3 has been investigated by means of 1H n.m.r., 13C CP/MAS n.m.r. and i.r. spectroscopy. It was confirmed that two of the four hydrogens in a unit of the phenyl ring are removed, which excludes the possibility of sulphonation. A direct intramolecular crosslink between neighbouring phenyl rings is shown to be the most probable modification. This forms a poly(benzothiophene) (PBT) molecule, consistent with the conductivity mechanism involving polarons. It is also pointed out that additional crosslinks via sulphuryl groups restrict the conjugation length, thus limiting the enhancement of conductivity." @default.
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- W2051330232 date "1986-09-01" @default.
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- W2051330232 title "SO3-doped poly(p-phenylene sulphide) I: A study of molecular structure using 1H N.M.R., 13C CP/MAS n.m.r. and i.r. spectroscopy" @default.
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- W2051330232 doi "https://doi.org/10.1016/0379-6779(86)90079-2" @default.
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