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- W2051340923 abstract "The resonances of the protonated carbons of [d(TAGCGCTA)]2 have been assigned by the two-dimensional proton-detected double-quantum heteronuclear correlation experiment [( 1H-13C]-DQCOSY). 13C-coupled and 13C-decoupled versions of the experiment were used. The assignment method is discussed in detail. The deoxyribose cross peaks segregate into five well-resolved regions, and the base cross peaks have distinct features that are helpful for assignments. The cross peaks from the 1H-13C pairs at the Cyd5, Ado2 and ThdCH3 base positions fall in separate regions of the spectrum from each other; they also are resolved from the closely spaced Ado8, Guo8, Cyd6 and Thd6. Additional parameters for distinction of the base signals are their differing J-coupling values and long-range coupling patterns." @default.
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- W2051340923 date "1988-04-01" @default.
- W2051340923 modified "2023-09-23" @default.
- W2051340923 title "<sup>13</sup>C NMR Assignments of the Protonated Carbons of [d(TAGCGCTA)]<sub>2</sub>by Two-Dimensional Proton-Detected Heteronuclear Correlation" @default.
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- W2051340923 doi "https://doi.org/10.1080/07391102.1988.10506450" @default.
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