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- W2051355312 abstract "Chemiluminescence spectra have been recorded for low-pressure, highly dilute, fuel-lean atomic oxygen flames of C2H2 and C3O2; under typical flame conditions the total pressure was 0.83 Torr with 1.1 mTorr of O atoms, 0.44 mTorr of O2, 0.20 mTorr of fuel, and the balance Ar. Spectral coverage was complete from 183 to 1500 nm for C2H2, and from 183 to 885 nm for C3O2. Strong CO a → X Cameron band emission was found to be the dominant feature of the chemiluminescence signature from 190 to 260 nm for C2H2 oxidation under these conditions, with distinct but relatively minor CO A → X fourth positive emission between 185 and 195 nm. There is strong emission from higher triplet states of CO throughout the visible and near-IR, with CO e → a, d → a, and a‘ → a emission features observed. Nearly identical CO emission spectra were obtained for both C2H2 and C3O2 fuels, which indicates that for both fuels the source of electronically excited CO is the C2O + O reaction. Quantification of emission yields for the four t..." @default.
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- W2051355312 date "1996-01-01" @default.
- W2051355312 modified "2023-09-24" @default.
- W2051355312 title "Formation of Triplet CO in Atomic Oxygen Flames of Acetylene and Carbon Suboxide" @default.
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- W2051355312 doi "https://doi.org/10.1021/jp950363z" @default.
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