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- W2051373369 abstract "Organic fluorescent hosts which can exhibit sensitive color and fluorescence changes upon formation of host-guest inclusion complexes in the crystalline state can be one of the most promising materials for the construction of desirable solid-state fluorescent system and are attractive materials for their potential applications in analytical and material sciences. For this purpose, we have designed and synthesized several kind of heterocyclic quinol-type fluorescent hosts, (benzofurano[1,2-d]naphthoquionl-type, benzo[kl]xanthenol-type, benzofurano[3,2-b]naphthoquinol-type, and imidazo[5,4-a]anthraquinol-type fluorophores) whose crystals exhibit a dramatic fluorescence enhancement upon inclusion of various kinds of organic solvent molecules. The magnitude of the solid-state fluorescence enhancement is greatly dependent on the enclathrated guest molecules. It is confirmed from the spectral data and the X-ray crystal structures that the destruction of the host-host π-π interactions by the enclathrated guest molecules is the main reason for the guest-dependent fluorescence enhancement behavior. Furthermore, we found that these heterocyclic quinol-type fluorescent clathrands exhibit color and fluorescence changes upon exposure to various solvent vapors both in the crystalline state and thin-film state. We believe that these results are useful for the development of new solid-emissive chemosensors and for the improvement of pigmentary solid-state fluorescence in the applied field of optoelectronic devices." @default.
- W2051373369 created "2016-06-24" @default.
- W2051373369 creator A5034160902 @default.
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- W2051373369 date "2009-09-15" @default.
- W2051373369 modified "2023-09-27" @default.
- W2051373369 title "ChemInform Abstract: Solid-State Photophysical Properties and Functional Characteristics of Heterocyclic Quinol-Type Fluorescent Hosts with Clathrate-Forming Ability" @default.
- W2051373369 cites W2951180774 @default.
- W2051373369 doi "https://doi.org/10.1002/chin.200937263" @default.
- W2051373369 hasPublicationYear "2009" @default.
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