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- W2051432246 abstract "Abstract The C1 and C2 stereocenters of α‐glucosaminides can be prepared by establishing the stereocenters in either order. For the former, a C2‐azido glucosyl donor is prepared first, and the restraining effect of a 4,6‐O‐benzylidene ring is used to induce α‐coupling. For the latter, the C1 linkage is prepared first by use of an n ‐pentenyl‐manno‐1,2‐orthoester donor which ensures (a) clean α‐coupling and (b) a convenient C2‐ester. The C2‐ester is replaced with a triflate leaving group, and nucleophilic displacement is effected by use of a hypervalent silicon azide." @default.
- W2051432246 created "2016-06-24" @default.
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- W2051432246 date "2000-12-01" @default.
- W2051432246 modified "2023-10-12" @default.
- W2051432246 title "Strategies for stereocontrol at C1 or C2 in syntheses of α-glucosaminides" @default.
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- W2051432246 doi "https://doi.org/10.1560/kdp7-d0ba-bn04-3h3a" @default.
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