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- W2051440349 abstract "Electrical conductivity technique has been employed to investigate the molecular interaction of aza-aromatics viz. pyridine, α-pikoline, β-picoline and γ-picoline with haloanils, namely chloranil, bromanil and fluranil. The stoichiometry of the charge transfer (CT) complexes has been established and molar conductivities of the complexes determined employing the method of Gutmann and Keyzer. A model has been proposed for determining the equilibrium constant ( K ) of 1 : 1 molecular complexes of CT type by conductometric measurements. The model involves the assumption: 1/σ = [(1 + K c 0 A )/q d K c 0 A ] (1/ c 0 D ) + (1/q d c 0 A ), where σ is the conductivity of the molecular complex, q d is the extent of depolarization of the complex, c 0 A ) and c 0 D ) are the initial concentrations of the acceptors and donors, respectively. The values of K and q d follows the expected trend of the conductometric parameters determined by the method of Gutmann and Keyzer as well as ionization potential of donors, thereby substantiating the validity of the model proposed. The observed and theoretical values of thermodynamic parameters for the aza-aromatic-chloranil systems that the interaction of aza-aromatics with haloanils is occurring through the lone pair of nitrogen ring." @default.
- W2051440349 created "2016-06-24" @default.
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- W2051440349 date "1993-01-01" @default.
- W2051440349 modified "2023-09-26" @default.
- W2051440349 title "Conductometric Studies of Molecular Complexes of Charge Transfer Type Formed between Aza-Aromatics and Haloanils" @default.
- W2051440349 doi "https://doi.org/10.1135/cccc19930783" @default.
- W2051440349 hasPublicationYear "1993" @default.
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