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- W2051450522 abstract "Trapping Reactions for Unstable [1-Chloro-2,2,2-trifluoro-1-(trifluoromethyl)ethyl] Dialkyl Phosphites The reaction of ClP(OR)2 1a–d (R = Me, Et; R–R = CH2CH2, CMe2CMe2) with hexafluoroacetone yields the thermally unstable phosphites ClC(CF3)2OP(OR)2 4a–d besides other products. Trimethyl phosphite converts 4a–d into the phosphates (MeO)2P(O)OC(CF3)2P(OR)2 (R = Me, Et) 5a and b and the phosphonates (MeO)2P(O)C(CF3)2OP(OR)2 (R–R = CH2CH2, CMe2CMe2) 5c and d, Compounds formed in an Arbuzov reaction." @default.
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- W2051450522 date "1988-02-01" @default.
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- W2051450522 title "Abfangreaktionen für unbeständige [1-Chlor-2,2,2-trifluor-1-(trifluormethyl)ethyl]dialkylphosphite" @default.
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- W2051450522 doi "https://doi.org/10.1002/cber.19881210228" @default.
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