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- W2051470527 abstract "A series of planar chiral asymmetric naphthalenediimide (NDI) cyclophanes (1–4) consisting of two different NDIs interlinked by rigid meta-dimethylenebenzene spacers was synthesized. A modular synthetic strategy based on the dichloro cyclophane 1 as common precursor gave a straightforward access to racemic mixtures of the NDIcyclophane dyes 2–4. In particular the substitution of both chlorine atoms of 1 by tert-butylsulfanyl-, methoxy- and piperidinyl-groups provided racemic mixtures of the fluorescent NDI cyclophane dyes 2, 3 and 4 respectively. Fluorescence spectroscopy revealed chemically tuneable intramolecular FRET properties, as the spectral overlap between the emission of the unsubstituted NDI and the absorption of the core-substituted NDI subunit of the cyclophane could be adjusted by the core substituents. The racemic nature of the samples of cyclophanes 2–4, and in the case of the di-tert-butylsulfanyl functionalized cyclophane 2 the enrichment of both enantiomers, was demonstrated by HPLC using a chiral stationary phase. The solid state structure of 2 was determined by X-ray analysis. A periodic arrangement of both enantiomers of the planar chiral cyclophane 2 in pillars such that NDI- and 2,6-core substituted NDI chromophores alternate periodically was observed." @default.
- W2051470527 created "2016-06-24" @default.
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- W2051470527 date "2009-01-01" @default.
- W2051470527 modified "2023-10-12" @default.
- W2051470527 title "Planar chiral asymmetric naphthalenediimide cyclophanes: synthesis, characterization and tunable FRET properties" @default.
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- W2051470527 cites W1973696945 @default.
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- W2051470527 cites W1974491454 @default.
- W2051470527 cites W1979860628 @default.
- W2051470527 cites W1980608493 @default.
- W2051470527 cites W1983443107 @default.
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- W2051470527 doi "https://doi.org/10.1039/b905945h" @default.
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