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- W2051473119 abstract "Abstract This experimental study describes efficient CO 2 capture by 2‐amino‐2‐methyl‐1‐propanol (AMP)/piperazine (PZ) in ethylene glycol monoethyl ether (EGMEE, 2‐ethoxyethanol) containing approximately 15 wt % of water. In these experiments, the solvent is continuously circulated between the absorber (packed‐bed reactor at 30, 40, or 45 °C) and the desorber (at 80, 85, or 90 °C). The CO 2 –solvent reaction equilibria have been investigated by using 13 C NMR spectroscopy, which provides confirmatory evidence that the formation of mono‐ and biscarbamate derivatives of PZ accounts for most of the CO 2 absorbed by the AMP/PZ/EGMEE/H 2 O blend. The solid‐state structures of AMP carbamate and of the carbonate salt of protonated AMP have been determined by using XRD. Both AMPCO 2 − and CO 3 2− species completely convert to the monoalkyl carbonates on dissolving the respective salts in methanol, ethanol, or ethylene glycol." @default.
- W2051473119 created "2016-06-24" @default.
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- W2051473119 date "2012-07-09" @default.
- W2051473119 modified "2023-10-18" @default.
- W2051473119 title "Improved Solvent Formulations for Efficient CO2 Absorption and Low-Temperature Desorption" @default.
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- W2051473119 doi "https://doi.org/10.1002/cssc.201200062" @default.
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