FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051497171> ?p ?o ?g. }

• W2051497171 endingPage "1000" @default.
• W2051497171 startingPage "986" @default.
• W2051497171 abstract "The compound Pt3Re2(CO)6(PBut3)3, 1, was obtained from the reaction of Re2(CO)10 with Pt(PBut3)2 in octane solvent at reflux. Compound 1 consists of a trigonal bipyramidal cluster of five metal atoms with three platinum atoms in the trigonal plane and the two rhenium atoms in the apical positions. The metal cluster is formally unsaturated by 10 electrons. Compound 1 sequentially adds 3 equiv of hydrogen at room temperature/1 atm to form the series of compounds Pt3Re2(CO)6(PBut3)3(μ-H)2, 2, Pt3Re2(CO)6(PBut3)3(μ-H)4, 3, and Pt3Re2(CO)6(PBut3)3(μ-H)6, 4. A small but significant kinetic isotope effect was observed, kH/kD = 1.3. The rate of addition of hydrogen is unaffected by the presence of a 20-fold excess of free PBut3 in solutions of 1. Compounds 2−4 each consist of a trigonal bipyramidal cluster of three platinum and two rhenium atoms similar to that of 1. The hydrido ligands in 2−4 bridge the platinum−rhenium bonds and are arranged to give structures having overall C2v symmetry for 2 and 3 and approximate D3h symmetry for 4. Some of the hydrido ligands were expelled from 4 in the form of hydrogen upon exposure of solutions to UV−vis irradiation to yield compound 3 and then 2 in reasonable yields, but the elimination of all hydrido ligands to yield 1 was achieved only under the most forcing UV irradiation and then only with a major loss of the complex due to decomposition. The electronic structures of 1−4 were investigated by DFT calculations. Additional DFT calculations have suggested some mechanisms for the activation of hydrogen at multicenter metal sites without ligand eliminations prior to the hydrogen additions." @default.
• W2051497171 created "2016-06-24" @default.
• W2051497171 creator A5042655264 @default.
• W2051497171 creator A5054254387 @default.
• W2051497171 creator A5058820456 @default.
• W2051497171 creator A5074786385 @default.
• W2051497171 date "2007-01-01" @default.
• W2051497171 modified "2023-09-23" @default.
• W2051497171 title "Photoreversible Multiple Additions of Hydrogen to a Highly Unsaturated Platinum−Rhenium Cluster Complex" @default.
• W2051497171 cites W1559291190 @default.
• W2051497171 cites W1964986996 @default.
• W2051497171 cites W1965378620 @default.
• W2051497171 cites W1968344479 @default.
• W2051497171 cites W1970529594 @default.
• W2051497171 cites W1973498680 @default.
• W2051497171 cites W1981745234 @default.
• W2051497171 cites W1983148800 @default.
• W2051497171 cites W1990495120 @default.
• W2051497171 cites W1996224669 @default.
• W2051497171 cites W1997173539 @default.
• W2051497171 cites W1998866028 @default.
• W2051497171 cites W2002892637 @default.
• W2051497171 cites W2007998078 @default.
• W2051497171 cites W2010243955 @default.
• W2051497171 cites W2020222164 @default.
• W2051497171 cites W2021480093 @default.
• W2051497171 cites W2034631530 @default.
• W2051497171 cites W2038047511 @default.
• W2051497171 cites W2042465329 @default.
• W2051497171 cites W2058676041 @default.
• W2051497171 cites W2067272205 @default.
• W2051497171 cites W2071873612 @default.
• W2051497171 cites W2072741235 @default.
• W2051497171 cites W2073698638 @default.
• W2051497171 cites W2077569697 @default.
• W2051497171 cites W2081277202 @default.
• W2051497171 cites W2083648896 @default.
• W2051497171 cites W2083993424 @default.
• W2051497171 cites W2093715047 @default.
• W2051497171 cites W2094304210 @default.
• W2051497171 cites W2094642658 @default.
• W2051497171 cites W2098205947 @default.
• W2051497171 cites W2101662302 @default.
• W2051497171 cites W2107443351 @default.
• W2051497171 cites W2111780926 @default.
• W2051497171 cites W2112345360 @default.
• W2051497171 cites W2117894566 @default.
• W2051497171 cites W2167383445 @default.
• W2051497171 cites W2949290443 @default.
• W2051497171 cites W2949742202 @default.
• W2051497171 cites W2950439666 @default.
• W2051497171 cites W2953003901 @default.
• W2051497171 cites W4242347576 @default.
• W2051497171 cites W4247505176 @default.
• W2051497171 doi "https://doi.org/10.1021/ja067028g" @default.
• W2051497171 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17243836" @default.
• W2051497171 hasPublicationYear "2007" @default.
• W2051497171 type Work @default.
• W2051497171 sameAs 2051497171 @default.
• W2051497171 citedByCount "38" @default.
• W2051497171 countsByYear W20514971712012 @default.
• W2051497171 countsByYear W20514971712013 @default.
• W2051497171 countsByYear W20514971712014 @default.
• W2051497171 countsByYear W20514971712015 @default.
• W2051497171 countsByYear W20514971712016 @default.
• W2051497171 countsByYear W20514971712017 @default.
• W2051497171 countsByYear W20514971712018 @default.
• W2051497171 countsByYear W20514971712022 @default.
• W2051497171 crossrefType "journal-article" @default.
• W2051497171 hasAuthorship W2051497171A5042655264 @default.
• W2051497171 hasAuthorship W2051497171A5054254387 @default.
• W2051497171 hasAuthorship W2051497171A5058820456 @default.
• W2051497171 hasAuthorship W2051497171A5074786385 @default.
• W2051497171 hasConcept C111592845 @default.
• W2051497171 hasConcept C115624301 @default.
• W2051497171 hasConcept C161790260 @default.
• W2051497171 hasConcept C164866538 @default.
• W2051497171 hasConcept C178790620 @default.
• W2051497171 hasConcept C179104552 @default.
• W2051497171 hasConcept C185592680 @default.
• W2051497171 hasConcept C199360897 @default.
• W2051497171 hasConcept C41008148 @default.
• W2051497171 hasConcept C505216180 @default.
• W2051497171 hasConcept C512968161 @default.
• W2051497171 hasConcept C518104683 @default.
• W2051497171 hasConcept C544153396 @default.
• W2051497171 hasConcept C75473681 @default.
• W2051497171 hasConcept C8010536 @default.
• W2051497171 hasConceptScore W2051497171C111592845 @default.
• W2051497171 hasConceptScore W2051497171C115624301 @default.
• W2051497171 hasConceptScore W2051497171C161790260 @default.
• W2051497171 hasConceptScore W2051497171C164866538 @default.
• W2051497171 hasConceptScore W2051497171C178790620 @default.
• W2051497171 hasConceptScore W2051497171C179104552 @default.
• W2051497171 hasConceptScore W2051497171C185592680 @default.
• W2051497171 hasConceptScore W2051497171C199360897 @default.
• W2051497171 hasConceptScore W2051497171C41008148 @default.
• W2051497171 hasConceptScore W2051497171C505216180 @default.

• next