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- W2051510908 abstract "In this paper, the vibrational spectra of kanemite are measured. The fact that infrared and Raman spectral bands are not coincident indicates that kanemite belongs to a space group with a center of symmetry. The observation of an IR band at 1167 cm−1 in kanemite suggests the existence of Si–O–Si linkages with a bond angle of approximately 180°. The strong Raman band at 465 cm−1 in the kanemite spectrum is associated with the six-membered rings of [SiO4] tetrahedra. The strong Raman band at 1060 cm−1 is consistent with the stretching vibrations of Q3 species (νSiO−). The broad band centered at 1015 cm−1 is assigned to the Q3 units involved in strong hydrogen bonding. Hydrogen bonding occurring in kanemite is also evident from a broad OH stretching band (3463 cm−1) observed in the IR spectrum. However, not all hydroxyl groups are involved in hydrogen bonding since a sharp OH stretching signal is observed at 3582 cm−1 in IR spectrum." @default.
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- W2051510908 date "1998-12-01" @default.
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- W2051510908 title "A vibrational spectroscopic study of kanemite" @default.
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- W2051510908 doi "https://doi.org/10.1016/s1387-1811(98)00270-4" @default.
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