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- W2051517170 abstract "Two different instruments were deployed to measure hydroperoxy radical (HO 2 ) and total peroxy radicals during May and June 2002 at a rural site located at Rock Springs near State College, Pennsylvania. One instrument was the Penn State Ground‐Based Tropospheric Hydrogen Oxides Sensor (GTHOS), which measured HO 2 by laser‐induced fluorescence (LIF) of OH following the chemical conversion of HO 2 to OH by adding NO. The other was the Peroxy Radical Chemical Ionization Mass Spectrometer (PerCIMS) instrument that provided HO 2 (HO 2 mode) or total peroxy radicals (HO x RO x mode) measurements. The two instruments were compared by exchanging calibration sources and by side‐by‐side ambient measurements. Excellent agreement was obtained in the calibration comparisons with the slope of a correlation plot close to 1.0 and a small intercept. Daily HO 2 measurements from GTHOS and PerCIMS (in HO 2 mode) on 4 days show that diurnal variations normally agreed to within about 40%. A comparison of HO 2 measured by GTHOS and HO x RO x measured by PerCIMS shows good correlation for both average diurnal variation and individual diurnal cycles. On average, HO 2 from GTHOS was about 0.66 times the HO x RO x from PerCIMS, meaning that organic peroxy radicals account for about one third of the total peroxy radicals in this environment." @default.
- W2051517170 created "2016-06-24" @default.
- W2051517170 creator A5000683611 @default.
- W2051517170 date "2003-10-09" @default.
- W2051517170 modified "2023-10-15" @default.
- W2051517170 title "Intercomparison of peroxy radical measurements at a rural site using laser-induced fluorescence and Peroxy Radical Chemical Ionization Mass Spectrometer (PerCIMS) techniques" @default.
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- W2051517170 doi "https://doi.org/10.1029/2003jd003644" @default.
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