FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051531627> ?p ?o ?g. }

• W2051531627 endingPage "779" @default.
• W2051531627 startingPage "771" @default.
• W2051531627 abstract "AbstractCarboxymethylcellulose(CMC)hydrogelformedbyionizingradiationathighlyconcentratedaqueoussolutionswasfoundtoundergoswellingdependingonthepHoftheswellingmedia.SwellingincreasesatneutralandbasicpHduetoionizationofcarboxymethylgroupsonsidechains.Thepresenceofchargesdevelopsrepulsiveforcesbetweenpolymerchainsofthenetworkcausingitsexpansion.Hydrogelinrelaxedstateaswellasdriedgelrevealsgoodmechanicalproperties.Itwasconsideredthatintermolecularcrosslinkingreactionsoccurbyaradicalroute.RadicalsplacedonanhydroglucoserepeatingunitaswellasonsidechainsweredistinguishedfromESRspectraofCMC.Astabledoubletsignal with 2.0mT splitting constant belongs to a radical placed on the a-carbon atom of the substituent group,R–O– d CH–COO – .Itwasassumedthatthisspeciesparticipatesinintermolecularcrosslinking.r 2003ElsevierLtd.Allrightsreserved. Keywords: Carboxymethylcellulose;Hydrogels;Crosslinking;Ionizingradiation;Radicals 1. IntroductionBasicrequirementsforpolymericabsorbentsarelargefluid uptake and high mechanical strength. These twodemandsareclearlyconflicting,andasuitablecompro-mise needs to be found. A high degree of swelling inaqueous systems can be achieved by using polyelec-trolytesbecauseofmobilecounterions presentinsuchgels develop a large swelling pressure (Florry, 1953).Thus,carboxymethylcellulose(CMC),whichisthemostpopularandthecheapestcelluloseethercanbeusedforthis purpose. It is an anionic linear polymer in whichoriginal H atoms of cellulose hydroxyl groups arereplaced by carboxymethyl substituent, –CH" @default.
• W2051531627 created "2016-06-24" @default.
• W2051531627 creator A5020397728 @default.
• W2051531627 creator A5028812814 @default.
• W2051531627 creator A5040598224 @default.
• W2051531627 creator A5041500945 @default.
• W2051531627 date "2003-12-01" @default.
• W2051531627 modified "2023-09-30" @default.
• W2051531627 title "Radiation crosslinking of carboxymethylcellulose of various degree of substitution at high concentration in aqueous solutions of natural pH" @default.
• W2051531627 cites W1526088078 @default.
• W2051531627 cites W1973169361 @default.
• W2051531627 cites W1976930865 @default.
• W2051531627 cites W1979975411 @default.
• W2051531627 cites W1986945581 @default.
• W2051531627 cites W1989011887 @default.
• W2051531627 cites W1995913170 @default.
• W2051531627 cites W1997989484 @default.
• W2051531627 cites W2002700102 @default.
• W2051531627 cites W2003535188 @default.
• W2051531627 cites W2020488264 @default.
• W2051531627 cites W2023507201 @default.
• W2051531627 cites W2039226544 @default.
• W2051531627 cites W2053529175 @default.
• W2051531627 cites W2060264466 @default.
• W2051531627 cites W2064096420 @default.
• W2051531627 cites W2066443946 @default.
• W2051531627 cites W2069340925 @default.
• W2051531627 cites W2072172174 @default.
• W2051531627 cites W2077513592 @default.
• W2051531627 cites W2080112208 @default.
• W2051531627 cites W2081442705 @default.
• W2051531627 cites W2090218026 @default.
• W2051531627 cites W2097883002 @default.
• W2051531627 cites W2130184438 @default.
• W2051531627 cites W2132893643 @default.
• W2051531627 cites W2140691410 @default.
• W2051531627 cites W2163315068 @default.
• W2051531627 cites W2480980796 @default.
• W2051531627 cites W4232677330 @default.
• W2051531627 cites W4255843229 @default.
• W2051531627 doi "https://doi.org/10.1016/s0969-806x(03)00403-1" @default.
• W2051531627 hasPublicationYear "2003" @default.
• W2051531627 type Work @default.
• W2051531627 sameAs 2051531627 @default.
• W2051531627 citedByCount "110" @default.
• W2051531627 countsByYear W20515316272012 @default.
• W2051531627 countsByYear W20515316272013 @default.
• W2051531627 countsByYear W20515316272014 @default.
• W2051531627 countsByYear W20515316272015 @default.
• W2051531627 countsByYear W20515316272016 @default.
• W2051531627 countsByYear W20515316272017 @default.
• W2051531627 countsByYear W20515316272018 @default.
• W2051531627 countsByYear W20515316272019 @default.
• W2051531627 countsByYear W20515316272020 @default.
• W2051531627 countsByYear W20515316272021 @default.
• W2051531627 countsByYear W20515316272022 @default.
• W2051531627 countsByYear W20515316272023 @default.
• W2051531627 crossrefType "journal-article" @default.
• W2051531627 hasAuthorship W2051531627A5020397728 @default.
• W2051531627 hasAuthorship W2051531627A5028812814 @default.
• W2051531627 hasAuthorship W2051531627A5040598224 @default.
• W2051531627 hasAuthorship W2051531627A5041500945 @default.
• W2051531627 hasConcept C121332964 @default.
• W2051531627 hasConcept C127413603 @default.
• W2051531627 hasConcept C13965031 @default.
• W2051531627 hasConcept C178790620 @default.
• W2051531627 hasConcept C184651966 @default.
• W2051531627 hasConcept C185592680 @default.
• W2051531627 hasConcept C199360897 @default.
• W2051531627 hasConcept C24890656 @default.
• W2051531627 hasConcept C2775997480 @default.
• W2051531627 hasConcept C2778220771 @default.
• W2051531627 hasConcept C41008148 @default.
• W2051531627 hasConcept C42360764 @default.
• W2051531627 hasConceptScore W2051531627C121332964 @default.
• W2051531627 hasConceptScore W2051531627C127413603 @default.
• W2051531627 hasConceptScore W2051531627C13965031 @default.
• W2051531627 hasConceptScore W2051531627C178790620 @default.
• W2051531627 hasConceptScore W2051531627C184651966 @default.
• W2051531627 hasConceptScore W2051531627C185592680 @default.
• W2051531627 hasConceptScore W2051531627C199360897 @default.
• W2051531627 hasConceptScore W2051531627C24890656 @default.
• W2051531627 hasConceptScore W2051531627C2775997480 @default.
• W2051531627 hasConceptScore W2051531627C2778220771 @default.
• W2051531627 hasConceptScore W2051531627C41008148 @default.
• W2051531627 hasConceptScore W2051531627C42360764 @default.
• W2051531627 hasIssue "5" @default.
• W2051531627 hasLocation W20515316271 @default.
• W2051531627 hasOpenAccess W2051531627 @default.
• W2051531627 hasPrimaryLocation W20515316271 @default.
• W2051531627 hasRelatedWork W2029913809 @default.
• W2051531627 hasRelatedWork W2065440283 @default.
• W2051531627 hasRelatedWork W2099417736 @default.
• W2051531627 hasRelatedWork W2748952813 @default.
• W2051531627 hasRelatedWork W2949183940 @default.
• W2051531627 hasRelatedWork W2952609894 @default.
• W2051531627 hasRelatedWork W2952768603 @default.
• W2051531627 hasRelatedWork W3005418856 @default.

• next