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- W2051533066 abstract "Abstract During the electroreduction of phthalic acid in aqueous solution with constant current density, the potential of the lead cathode is shifted by about 0·3 V in cathodic direction. After about 1 hr, an absolutely stationary potential is reached. This is caused by the growth of porous organic films, constituted of insoluble dimers, which are formed with about 1 per cent current efficiency as byproducts. A mechanism is proposed for the steady state porosity of this film (thickness ∼4 μm) after some time. In the course of galvanostatic electroreduction of ammoniumphthalamate in slightly alkaline solution, the potential of the lead cathode tends to become more anodic. It was shown by model experiments, that electrodeposition traces of metal, especially chromium, causes this potential shift due to their influence on the hydrogen overvoltage." @default.
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- W2051533066 date "1975-05-01" @default.
- W2051533066 modified "2023-09-25" @default.
- W2051533066 title "Potential time behaviour of lead cathodes in the electroreduction of phthalic acid" @default.
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- W2051533066 doi "https://doi.org/10.1016/0013-4686(75)90018-3" @default.
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