FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051567759> ?p ?o ?g. }

• W2051567759 endingPage "6010" @default.
• W2051567759 startingPage "6002" @default.
• W2051567759 abstract "Reaction of Na2MoVIO4·2H2O with (NH4)2SO3 in the mixed-solvent system H2O/CH3CN (pH = 5) resulted in the formation of the tetranuclear cluster (NH4)4[Mo4VISO16]·H2O (1), while the same reaction in acidic aqueous solution (pH = 5) yielded (NH4)4[Mo5VIS2O21]·3H2O (2). Compound {(H2bipy)2[Mo5VIS2O21]·H2O}x (3) was obtained from the reaction of aqueous acidic solution of Na2MoVIO4·2H2O with (NH4)2SO3 (pH = 2.5) and 4,4‘-bipyridine (4,4‘-bipy). The mixed metal/sulfite species (NH4)7[CoIII(Mo2VO4)(NH3)(SO3)6]·4H2O (4) was synthesized by reacting Na2MoVIO4·2H2O with CoCl2·6H2O and (NH4)2SO3 with precise control of pH (5.3) through a redox reaction. The X-ray crystal structures of compounds 1, 2, and 4 were determined. The structure of compound 1 consists of a ring of four alternately face- and edge-sharing MoVIO6 octahedra capped by the trigonal pyramidal sulfite anion, while at the base of the Mo4 ring is an oxo group which is asymmetrically shared by all four molybdenum atoms. Compound 3 is based on the Strandberg-type heteropolyion [Mo5VIS2O21]4-, and these coordinatively saturated clusters are joined by diprotonated 4,4‘-H2bipy2+ through strong hydrogen bonds. Compound 3 crystallizes in the chiral space group C2. The structure of compound 4 consists of a novel trinuclear [CoIIIMo2VSO32-] cluster. The chiral compound 3 exhibits nonlinear optical (NLO) and photoluminescence properties. The assignment of the sulfite bands in the IR spectrum of 4 has been carried out by density functional calculations. The cobalt in 4 is a d6 octahedral low-spin metal atom as it was evidenced by magnetic susceptibility measurements, cw EPR, BVS, and DFT calculations. The IR and solid-state UV−vis spectra as well as the thermogravimetric analyses of compounds 1−4 are also reported." @default.
• W2051567759 created "2016-06-24" @default.
• W2051567759 creator A5002881586 @default.
• W2051567759 creator A5013043945 @default.
• W2051567759 creator A5019027316 @default.
• W2051567759 creator A5022951412 @default.
• W2051567759 creator A5036328768 @default.
• W2051567759 creator A5045324658 @default.
• W2051567759 creator A5064154101 @default.
• W2051567759 creator A5081173597 @default.
• W2051567759 creator A5091700772 @default.
• W2051567759 date "2007-06-26" @default.
• W2051567759 modified "2023-10-12" @default.
• W2051567759 title "Polyoxomolybdenum(V/VI)−Sulfite Compounds: Synthesis, Structural, and Physical Studies" @default.
• W2051567759 cites W1872714560 @default.
• W2051567759 cites W1964837435 @default.
• W2051567759 cites W1966792574 @default.
• W2051567759 cites W1975068314 @default.
• W2051567759 cites W1976318412 @default.
• W2051567759 cites W1977266914 @default.
• W2051567759 cites W1980529128 @default.
• W2051567759 cites W1981926142 @default.
• W2051567759 cites W1983632722 @default.
• W2051567759 cites W1983770278 @default.
• W2051567759 cites W1984455963 @default.
• W2051567759 cites W1985410373 @default.
• W2051567759 cites W2000070548 @default.
• W2051567759 cites W2000469226 @default.
• W2051567759 cites W2004767114 @default.
• W2051567759 cites W2011788455 @default.
• W2051567759 cites W2015723183 @default.
• W2051567759 cites W2017387213 @default.
• W2051567759 cites W2025157535 @default.
• W2051567759 cites W2041390647 @default.
• W2051567759 cites W2041893040 @default.
• W2051567759 cites W2043327592 @default.
• W2051567759 cites W2049079467 @default.
• W2051567759 cites W2058994179 @default.
• W2051567759 cites W2064056813 @default.
• W2051567759 cites W2074019256 @default.
• W2051567759 cites W2082034983 @default.
• W2051567759 cites W2082712943 @default.
• W2051567759 cites W2085698824 @default.
• W2051567759 cites W2093165316 @default.
• W2051567759 cites W2094642658 @default.
• W2051567759 cites W2096145675 @default.
• W2051567759 cites W2097270182 @default.
• W2051567759 cites W2101741054 @default.
• W2051567759 cites W2101947989 @default.
• W2051567759 cites W2102430506 @default.
• W2051567759 cites W2114307679 @default.
• W2051567759 cites W2116943405 @default.
• W2051567759 cites W2127369719 @default.
• W2051567759 cites W2127829736 @default.
• W2051567759 cites W2128873760 @default.
• W2051567759 cites W2137220265 @default.
• W2051567759 cites W2139849456 @default.
• W2051567759 cites W2143981217 @default.
• W2051567759 cites W2146474564 @default.
• W2051567759 cites W2147406122 @default.
• W2051567759 cites W2150314210 @default.
• W2051567759 cites W2159921116 @default.
• W2051567759 cites W2277843176 @default.
• W2051567759 cites W2949476507 @default.
• W2051567759 cites W2950337686 @default.
• W2051567759 cites W2950547475 @default.
• W2051567759 cites W2951429531 @default.
• W2051567759 cites W2951818801 @default.
• W2051567759 cites W2952078425 @default.
• W2051567759 cites W2952598513 @default.
• W2051567759 cites W2953070736 @default.
• W2051567759 cites W3004606457 @default.
• W2051567759 cites W4206332030 @default.
• W2051567759 cites W605170700 @default.
• W2051567759 doi "https://doi.org/10.1021/ic700460b" @default.
• W2051567759 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17592836" @default.
• W2051567759 hasPublicationYear "2007" @default.
• W2051567759 type Work @default.
• W2051567759 sameAs 2051567759 @default.
• W2051567759 citedByCount "25" @default.
• W2051567759 countsByYear W20515677592012 @default.
• W2051567759 countsByYear W20515677592013 @default.
• W2051567759 countsByYear W20515677592015 @default.
• W2051567759 countsByYear W20515677592016 @default.
• W2051567759 countsByYear W20515677592018 @default.
• W2051567759 countsByYear W20515677592019 @default.
• W2051567759 countsByYear W20515677592022 @default.
• W2051567759 crossrefType "journal-article" @default.
• W2051567759 hasAuthorship W2051567759A5002881586 @default.
• W2051567759 hasAuthorship W2051567759A5013043945 @default.
• W2051567759 hasAuthorship W2051567759A5019027316 @default.
• W2051567759 hasAuthorship W2051567759A5022951412 @default.
• W2051567759 hasAuthorship W2051567759A5036328768 @default.
• W2051567759 hasAuthorship W2051567759A5045324658 @default.
• W2051567759 hasAuthorship W2051567759A5064154101 @default.
• W2051567759 hasAuthorship W2051567759A5081173597 @default.
• W2051567759 hasAuthorship W2051567759A5091700772 @default.
• W2051567759 hasConcept C112887158 @default.

• next