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- W2051575127 abstract "Abstract The ν4 fundamental band (CO2 antisymmetric stretching mode) of the FCO2 radical in the ground electronic state X ˜ 2 B 2 has been recorded by Fourier-transform infrared spectroscopy at an effective resolution of 0.003 cm−1 between 1040 and 1130 cm−1. FCO2 was generated by vacuum flash pyrolysis at about 350 °C of FC(O)OO(O)CF. More than 3300 ro-vibrational transitions have been assigned, which involved levels with N′ up to 56 and K a ′ up to 38. The observed Doppler-broadened spectrum was analyzed to yield accurate values of the band origin (1094.142210(27) cm−1, one standard error in parentheses), the rotational constants, the quartic centrifugal distortion constants and electron spin-rotation interaction parameters in the v4 = 1 state. Large variations of the centrifugal distortion parameters ΔK (+26%), ΔNK (−1463%) and δK (−10%) upon excitation of the ν4 vibration have been observed." @default.
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- W2051575127 date "2012-08-01" @default.
- W2051575127 modified "2023-09-25" @default.
- W2051575127 title "High-resolution FTIR study of the CO stretching band ν4 of the fluoroformyloxyl radical, FCO2" @default.
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- W2051575127 doi "https://doi.org/10.1016/j.jms.2012.06.015" @default.
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