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• W2051581828 abstract "Abstract We investigate the possible existence of crystalline alkali metal orthocarbonates, A 4 CO 4 , where A=Li, Na, K, Rb, and Cs. We study the equilibrium between the possible modifications of the orthocarbonate A 4 CO 4 and the binary mixture of the possible modifications of the alkali oxide A 2 O and those of the alkali metal carbonate A 2 CO 3 as function of pressure. In all cases, the orthocarbonate should be stable at sufficiently high pressure ranging from 22–32 GPa (Rb 4 CO 4 ) to 200–220 GPa (Cs 4 CO 4 )." @default.
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• W2051581828 date "2007-08-29" @default.
• W2051581828 modified "2023-10-18" @default.
• W2051581828 title "Possible Existence of Alkali Metal Orthocarbonates at High Pressure" @default.
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• W2051581828 doi "https://doi.org/10.1002/chem.200601637" @default.
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