Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051589495> ?p ?o ?g. }
- W2051589495 endingPage "1762" @default.
- W2051589495 startingPage "1757" @default.
- W2051589495 abstract "Abstract A novel aldol reaction of alkenyl trichloroacetates with α‐keto esters was realized by using dibutyltin dimethoxide as a catalyst, which was regenerated by the addition of methanol. The reaction was found to be remarkably accelerated by the addition of a catalytic amount of a bidentate phosphine⋅silver(I) complex. Use of the BINAP⋅silver triflate (AgOTf) complex as the chiral co‐catalyst resulted in the formation of optically active aldol products possessing a chiral tertiary carbon with up to 93% ee . This catalytic method was further applied to the asymmetric reaction of diketene with methyl benzoylformate." @default.
- W2051589495 created "2016-06-24" @default.
- W2051589495 creator A5014759451 @default.
- W2051589495 creator A5043024558 @default.
- W2051589495 creator A5069749535 @default.
- W2051589495 creator A5073365038 @default.
- W2051589495 date "2009-08-01" @default.
- W2051589495 modified "2023-10-18" @default.
- W2051589495 title "Asymmetric Aldol Reaction of Ketones with Alkenyl Trichloroacetates Catalyzed by Dibutyltin Dimethoxide and BINAP⋅Silver(I) Complex: Construction of a Chiral Tertiary Carbon Center" @default.
- W2051589495 cites W106680043 @default.
- W2051589495 cites W1518457161 @default.
- W2051589495 cites W1968527533 @default.
- W2051589495 cites W1974448032 @default.
- W2051589495 cites W1975276503 @default.
- W2051589495 cites W1978009396 @default.
- W2051589495 cites W1980824974 @default.
- W2051589495 cites W1981249397 @default.
- W2051589495 cites W1985846640 @default.
- W2051589495 cites W1987452125 @default.
- W2051589495 cites W1993194475 @default.
- W2051589495 cites W1994763564 @default.
- W2051589495 cites W1997251213 @default.
- W2051589495 cites W1997513452 @default.
- W2051589495 cites W2005705813 @default.
- W2051589495 cites W2010287421 @default.
- W2051589495 cites W2010717359 @default.
- W2051589495 cites W2013695548 @default.
- W2051589495 cites W2019408798 @default.
- W2051589495 cites W2020202656 @default.
- W2051589495 cites W2021776049 @default.
- W2051589495 cites W2032898714 @default.
- W2051589495 cites W2036492953 @default.
- W2051589495 cites W2036940424 @default.
- W2051589495 cites W2037894507 @default.
- W2051589495 cites W2038578179 @default.
- W2051589495 cites W2054878658 @default.
- W2051589495 cites W2056288228 @default.
- W2051589495 cites W2063180079 @default.
- W2051589495 cites W2067510313 @default.
- W2051589495 cites W2078075918 @default.
- W2051589495 cites W2080896693 @default.
- W2051589495 cites W2086199316 @default.
- W2051589495 cites W2088182340 @default.
- W2051589495 cites W2092448522 @default.
- W2051589495 cites W2098485753 @default.
- W2051589495 cites W2099168233 @default.
- W2051589495 cites W2112316234 @default.
- W2051589495 cites W2130609245 @default.
- W2051589495 cites W2130931310 @default.
- W2051589495 cites W2134402534 @default.
- W2051589495 cites W2154626584 @default.
- W2051589495 cites W2160958272 @default.
- W2051589495 cites W2167484721 @default.
- W2051589495 cites W2176412165 @default.
- W2051589495 cites W2178854976 @default.
- W2051589495 cites W2312191036 @default.
- W2051589495 cites W2949241209 @default.
- W2051589495 cites W2949774588 @default.
- W2051589495 cites W2950620248 @default.
- W2051589495 cites W2950791057 @default.
- W2051589495 cites W2952501926 @default.
- W2051589495 cites W3023061564 @default.
- W2051589495 cites W3141043953 @default.
- W2051589495 cites W35581340 @default.
- W2051589495 cites W4210991742 @default.
- W2051589495 cites W4230905811 @default.
- W2051589495 cites W4233575615 @default.
- W2051589495 cites W4239721228 @default.
- W2051589495 doi "https://doi.org/10.1002/adsc.200900437" @default.
- W2051589495 hasPublicationYear "2009" @default.
- W2051589495 type Work @default.
- W2051589495 sameAs 2051589495 @default.
- W2051589495 citedByCount "23" @default.
- W2051589495 countsByYear W20515894952012 @default.
- W2051589495 countsByYear W20515894952013 @default.
- W2051589495 countsByYear W20515894952014 @default.
- W2051589495 countsByYear W20515894952015 @default.
- W2051589495 countsByYear W20515894952016 @default.
- W2051589495 countsByYear W20515894952017 @default.
- W2051589495 countsByYear W20515894952018 @default.
- W2051589495 countsByYear W20515894952021 @default.
- W2051589495 crossrefType "journal-article" @default.
- W2051589495 hasAuthorship W2051589495A5014759451 @default.
- W2051589495 hasAuthorship W2051589495A5043024558 @default.
- W2051589495 hasAuthorship W2051589495A5069749535 @default.
- W2051589495 hasAuthorship W2051589495A5073365038 @default.
- W2051589495 hasConcept C115624301 @default.
- W2051589495 hasConcept C146686406 @default.
- W2051589495 hasConcept C155647269 @default.
- W2051589495 hasConcept C161790260 @default.
- W2051589495 hasConcept C178516000 @default.
- W2051589495 hasConcept C178790620 @default.
- W2051589495 hasConcept C185592680 @default.
- W2051589495 hasConcept C188027245 @default.
- W2051589495 hasConcept C21774173 @default.
- W2051589495 hasConcept C2778270430 @default.
- W2051589495 hasConcept C2778659974 @default.
- W2051589495 hasConcept C61156836 @default.