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- W2051615785 abstract "[Ru(CN)5NO]2− can be excited selectively by two very long-lived electronic metastable states (MSI and MSII) by irradiation at low temperature with blue-near UV light. Upon excitation to MSI and MSII states, CN and NO modes suffer frequency down-shifts, a fact which implies softening of the named bonds. Shifts of vibrational modes of the RuNO group are far larger than shifts of CN modes, a fact that indicates that the metastable states involve electronic transitions mainly located at that group. The MSI and MSII states decay when heating at two different onset temperatures TI < TII. A thermally driven MSI-to-MSII excitation transfer process taking place in the temperature range TII > T > TI shows that MSII is energetically below MSI." @default.
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- W2051615785 date "1997-02-01" @default.
- W2051615785 modified "2023-10-11" @default.
- W2051615785 title "Infrared absorption spectra of electronically excited long-lived metastable states in Na2[Ru(CN)5NO]·2H2O" @default.
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- W2051615785 doi "https://doi.org/10.1016/s0038-1098(96)00616-3" @default.
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