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• W2051629902 abstract "Defect curvature was developed based on our previous proposed direction curvature theory. Defect curvature, as a universal criterion, was used to identify reactivities of mono- and di-vacancies in single-walled carbon nanotubes. Calculated results at B3LYP/6-31G* level showed that, regardless of mono- and di-vacancies, vacancy formation energies Ef decreased with increasing defect curvature KV1 (for mono-vacancies) or KV2 (for di-vacancies). Each defect model of mono-vacancies had two types of structural products. However, each defect model of di-vacancies was only corresponding to one structural product. In mono- or di-vacancies, large included angles between new formed C-C bonds (for mono-vacancies) or the linked C-C bonds of the 5-ring and 8-ring (for di-vacancies) and the tubular axis were corresponding to short C-C bonds and small Ef. These product structures for di-vacancies were related to the magnitude of KV2." @default.
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• W2051629902 date "2015-03-01" @default.
• W2051629902 modified "2023-10-16" @default.
• W2051629902 title "Curvature effect of vacancies in single-walled carbon nanotubes" @default.
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• W2051629902 doi "https://doi.org/10.1016/j.susc.2014.11.018" @default.
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