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- W2051641036 abstract "The {100} and {001} surfaces of La2CuO4 and Nd2CuO4 are perpendicular and parallel to their (super)conducting CuO2 planes. Surface and intergranular conductivity and weak links will be influenced by the integrity of these surfaces. This integrity will evolve during the processing of the semi-conducting precursor compounds and will be “frozen-in” when the newly formed lanthanum copper oxide is cooled below the superconducting transition temperature. Therefore, the structures and stabilities of the La2CuO4 surfaces and the effect of impurity segregation (Ca2+, Sr2+, Ba2+, Ce4+ and Th4+) at these surfaces have been investigated by static lattice simulation. The greatest perturbation of the CuO2 planes in the pure materials is predicted at the {100} surface of La2CuO4, the depth of which is comparable to the coherence length of the superconducting phases. Impurity segregation at {100} surface copper sites of La2CuO4 is also predicted, in contrast to the other surfaces." @default.
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- W2051641036 date "1995-03-01" @default.
- W2051641036 modified "2023-09-27" @default.
- W2051641036 title "The calculated structure, stability and composition of the low index surfaces of La2CuO4 and Nd2CuO4" @default.
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- W2051641036 doi "https://doi.org/10.1016/0039-6028(94)00789-6" @default.
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