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• W2051667721 startingPage "1248" @default.
• W2051667721 abstract "Monolayers of molecular oxygen physically adsorbed on single-crystal graphite have been studied using low-energy electron diffraction (LEED). The lattice parameters for the low-coverage oblique ensuremath{delta} phase and the higher-coverage centered-rectangular ${ensuremath{delta}}^{mathrm{*}}$ phase are presented as a function of density and compared with x-ray studies. New information about the ensuremath{delta}' phase (which is oriented differently on the substrate) indicates that it may be an equilibrium phase. Three different phases are observed at temperatures above those where the ensuremath{delta}, ${ensuremath{delta}}^{mathrm{*}}$, or ensuremath{delta}' phases exist: a low-coverage liquid, an intermediate-coverage ensuremath{theta} phase, and a high-coverage fluid phase. The liquid and fluid phases have molecular-axis disorder, sufficient short-range order to produce LEED patterns, and bond-orientational order. We discuss the properties of these phases and the nature of the ensuremath{theta} phase, which we believe is a two-dimensional solid with molecular-axis disorder. Our data provide a detailed monolayer density-temperature phase diagram." @default.
• W2051667721 created "2016-06-24" @default.
• W2051667721 creator A5013910051 @default.
• W2051667721 creator A5039478299 @default.
• W2051667721 date "1987-07-15" @default.
• W2051667721 modified "2023-09-25" @default.
• W2051667721 title "Low-energy electron diffraction study of molecular oxygen physisorbed on graphite" @default.
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• W2051667721 doi "https://doi.org/10.1103/physrevb.36.1248" @default.
• W2051667721 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9942935" @default.
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