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• W2051707013 abstract "In order to overcome the difficulties in explaining the zero-field splitting and its stress (along the C3 axis) and hydrostatic pressure dependence for Na2ZnCl4·3H2O:Mn2+ crystal, which arise in previous work, we assume, in this paper, that the Mn2+ ion does not occupy the exact substitutional position of Zn2+ ion in Na2ZnCl4·3H2O, but is displaced about 0.3 Å on the C3, axis. Based on this, the zero-field splitting and its stress and pressure dependence have been calculated using the superposition model (and also the spin-orbit coupling mechanism), the results show reasonable agreement with the experimental findings." @default.
• W2051707013 created "2016-06-24" @default.
• W2051707013 creator A5060395477 @default.
• W2051707013 date "1993-11-01" @default.
• W2051707013 modified "2023-10-17" @default.
• W2051707013 title "Theoretical investigations of the zero-field splitting and its stress and pressure dependence for Mn2+ in Na2ZnCl4·3H2O crystal" @default.
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• W2051707013 doi "https://doi.org/10.1016/0022-3697(93)90353-s" @default.
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