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- W2051726598 abstract "The reaction between tungsten and bromine has been studied in the temperature interval between 1000 and 1500 K by means of a Knudsen double cell connected to a mass spectrometer. At pressures of bromine between 6 and 50 torr in the reaction cell only WBr4(g) is formed while at higher pressures formation of W2Br6(g) could be observed as the result of a secondary gas-phase reaction. From the measured intensities of different ions the pressure-temperature curve obtained for WBr4(g) exhibits abnormalities which could be explained in terms of the reaction kinetics leading to equilibrium conditions above 1270 K. On the basis of these considerations ΔH4o (−36.7 ± 1.7 kcal/mole), ΔGTo(−8.6 ± 0.6 kcal/mole) and ΔSTo(−21.3 ± 1 e.u.) have been obtained and compared with some thermodynamic data calculated using the third-law method." @default.
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- W2051726598 title "Mass spectrometric investigation of reaction between tungsten and bromine at high temperature" @default.
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- W2051726598 doi "https://doi.org/10.1016/0022-1902(79)80041-x" @default.
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