Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051760722> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2051760722 abstract "1-Phenylseleno-2-(p-toluenesulfonyl)ethyne (1) is an effective dienophile and dipolarophile. It underwent facile Diels−Alder reactions with a variety of dienes to afford vicinal sulfone- and selenide-functionalized 1,4-cyclohexadienes. Unexpected regiochemistry that is the opposite of what is obtained with simple acetylenic sulfones was observed with several unsymmetrical dienes containing methyl or methoxy substituents at the 1- or 2-position. Acetylene 1 reacted with (trimethylsilyl)methyl azide, diazomethane, and 2,4,6-trimethylbenzonitrile N-oxide via 1,3-dipolar cycloadditions to afford the corresponding triazole, 1,2-diazole, and isoxazole products. It also underwent an ene reaction with β-pinene that showed anomalous regiochemistry compared to other acetylenic sulfones. The Diels−Alder cycloadducts obtained from the reaction of 1 with 2,3-dimethyl-1,3-butadiene and 1,3-cyclohexadiene were readily converted into the corresponding β-keto sulfones and ketones, thus rendering 1 as the synthetic equival..." @default.
- W2051760722 created "2016-06-24" @default.
- W2051760722 creator A5006852792 @default.
- W2051760722 creator A5009061002 @default.
- W2051760722 creator A5028675199 @default.
- W2051760722 creator A5050446508 @default.
- W2051760722 creator A5063689747 @default.
- W2051760722 date "2010-06-10" @default.
- W2051760722 modified "2023-09-25" @default.
- W2051760722 title "ChemInform Abstract: Cycloaddition Reactions of 1-Phenylseleno-2-(p-toluenesulfonyl)ethyne." @default.
- W2051760722 cites W2951459134 @default.
- W2051760722 doi "https://doi.org/10.1002/chin.200008047" @default.
- W2051760722 hasPublicationYear "2010" @default.
- W2051760722 type Work @default.
- W2051760722 sameAs 2051760722 @default.
- W2051760722 citedByCount "0" @default.
- W2051760722 crossrefType "journal-article" @default.
- W2051760722 hasAuthorship W2051760722A5006852792 @default.
- W2051760722 hasAuthorship W2051760722A5009061002 @default.
- W2051760722 hasAuthorship W2051760722A5028675199 @default.
- W2051760722 hasAuthorship W2051760722A5050446508 @default.
- W2051760722 hasAuthorship W2051760722A5063689747 @default.
- W2051760722 hasConcept C121349320 @default.
- W2051760722 hasConcept C155647269 @default.
- W2051760722 hasConcept C161790260 @default.
- W2051760722 hasConcept C171811041 @default.
- W2051760722 hasConcept C178790620 @default.
- W2051760722 hasConcept C185592680 @default.
- W2051760722 hasConcept C2777000832 @default.
- W2051760722 hasConcept C2778806918 @default.
- W2051760722 hasConcept C2779325354 @default.
- W2051760722 hasConcept C2779664164 @default.
- W2051760722 hasConcept C2780374730 @default.
- W2051760722 hasConcept C2781269603 @default.
- W2051760722 hasConcept C59759590 @default.
- W2051760722 hasConceptScore W2051760722C121349320 @default.
- W2051760722 hasConceptScore W2051760722C155647269 @default.
- W2051760722 hasConceptScore W2051760722C161790260 @default.
- W2051760722 hasConceptScore W2051760722C171811041 @default.
- W2051760722 hasConceptScore W2051760722C178790620 @default.
- W2051760722 hasConceptScore W2051760722C185592680 @default.
- W2051760722 hasConceptScore W2051760722C2777000832 @default.
- W2051760722 hasConceptScore W2051760722C2778806918 @default.
- W2051760722 hasConceptScore W2051760722C2779325354 @default.
- W2051760722 hasConceptScore W2051760722C2779664164 @default.
- W2051760722 hasConceptScore W2051760722C2780374730 @default.
- W2051760722 hasConceptScore W2051760722C2781269603 @default.
- W2051760722 hasConceptScore W2051760722C59759590 @default.
- W2051760722 hasLocation W20517607221 @default.
- W2051760722 hasOpenAccess W2051760722 @default.
- W2051760722 hasPrimaryLocation W20517607221 @default.
- W2051760722 hasRelatedWork W1603592352 @default.
- W2051760722 hasRelatedWork W1992622681 @default.
- W2051760722 hasRelatedWork W2005478907 @default.
- W2051760722 hasRelatedWork W2065816919 @default.
- W2051760722 hasRelatedWork W2070307662 @default.
- W2051760722 hasRelatedWork W2071145199 @default.
- W2051760722 hasRelatedWork W2082248715 @default.
- W2051760722 hasRelatedWork W2087324199 @default.
- W2051760722 hasRelatedWork W2142046226 @default.
- W2051760722 hasRelatedWork W2147584222 @default.
- W2051760722 hasRelatedWork W2949532777 @default.
- W2051760722 hasRelatedWork W2949534875 @default.
- W2051760722 hasRelatedWork W2950251266 @default.
- W2051760722 hasRelatedWork W2950699940 @default.
- W2051760722 hasRelatedWork W2950880713 @default.
- W2051760722 hasRelatedWork W2951459134 @default.
- W2051760722 hasRelatedWork W2951474469 @default.
- W2051760722 hasRelatedWork W2951938185 @default.
- W2051760722 hasRelatedWork W2952269615 @default.
- W2051760722 hasRelatedWork W2952834925 @default.
- W2051760722 isParatext "false" @default.
- W2051760722 isRetracted "false" @default.
- W2051760722 magId "2051760722" @default.
- W2051760722 workType "article" @default.