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• W2051795014 startingPage "1335" @default.
• W2051795014 abstract "Autoionization probabilities of doubly excited atoms with one electron in a large-l Rydberg state are investigated through first-order perturbation theory in a single-configuration approach. In the framework of the jk-coupling scheme, the formalism takes into account multipoles higher than dipoles in the electronic interaction and exchange effects. Exchange effects are computed using the Froese method for Slater integrals and are demonstrated to be significant as long as l5. The essential importance of fine-structure transitions when the outer electron is in a large-l state is emphasized. Comparison with available experimental data shows that Slater integrals are reliably computed and that fair agreement is generally obtained for g states, while even strongly autoionizing f states are at least qualitatively represented. Correlation effects may explain some remaining disagreement with the measured autoionization widths." @default.
• W2051795014 created "2016-06-24" @default.
• W2051795014 creator A5052006999 @default.
• W2051795014 date "1994-08-01" @default.
• W2051795014 modified "2023-09-23" @default.
• W2051795014 title "Exchange and fine-structure effects in autoionization of large-angular-momentum doubly excited Rydberg states" @default.
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• W2051795014 doi "https://doi.org/10.1103/physreva.50.1335" @default.
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