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- W2051844083 abstract "The concentration dependence of FTIR and UV spectra of 2-hydroxypyridine (HP) and 6-chloro-2-hydroxypyridine was measured in CHCl3 and CCl4 in order to elucidate their tautomeric (enol-keto) equilibrium and to determine the association constants. The time dependence of FTIR spectra of 1,3-cyclohexanedione and 2-methyl-1,3-cyclohexanedione (MCHD) was also measured in CHCl3 solution. The (enol-keto) interconversion in MCHD took about a day, indicating that the monomolecular process is very slow. The crystal structure of the 1:1 complex of HP and lauric acid was determined by X-ray analysis. In this complex, HP occurs in dimeric keto-form similar to that formed in solution, although HP in solid state exists in the polymeric keto-form." @default.
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- W2051844083 date "1996-12-01" @default.
- W2051844083 modified "2023-09-24" @default.
- W2051844083 title "Fourier transform infrared spectrometric study of tautomeric (enol-keto) and dimeric equilibria in 2-hydroxypyridines and 1,3-cyclohexanediones in CHCl3 and/or CCl4 solutions" @default.
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- W2051844083 doi "https://doi.org/10.1016/0924-2031(96)00038-0" @default.
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