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- W2051870446 abstract "The gas phase reactions of carbon monoxide with small mass-selected clusters of palladium, Pdx+ (x = 2–7), and their oxides, PdxO+ (x = 2–7) and PdxO2+ (x = 4–6), have been investigated in a radio frequency ion trap operated under multi-collision conditions. The bare palladium clusters were found to readily adsorb CO yielding a highly size dependent product pattern. Most interestingly, the reactions of the pre-oxidized palladium clusters with CO lead to very similar product distributions of Pdx(CO)z+ complexes as in the case of the corresponding pure Pdx+ clusters. Consequently, it has been concluded that the investigated palladium oxide clusters efficiently oxidize CO under formation of the bare clusters, which further adsorb CO molecules yielding the previously observed Pdx(CO)z+ product complex distributions. This CO combustion reaction has been observed even at temperatures as low as 100 K. However, for Pd2O+, Pd6O+, Pd6O2+, and Pd7O+ a competing reaction channel yielding palladium oxide carbonyls PdxO(CO)z+ could be detected. The latter adsorption reaction may even hamper the CO combustion under certain reaction conditions and indicates enhanced activation barriers involved in the CO oxidation and/or the CO2 elimination process on these clusters." @default.
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- W2051870446 date "2012-01-01" @default.
- W2051870446 modified "2023-09-25" @default.
- W2051870446 title "Reactions of carbon monoxide with free palladium oxide clusters: strongly size dependent competition between adsorption and combustion" @default.
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- W2051870446 doi "https://doi.org/10.1039/c2cp23976k" @default.
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