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• W2051902397 abstract "A new tether for small molecule synthesis is reported. This functionally active tether mediates the desymmetrization of a pseudo-C2-symmetric tris-allylic phosphate triester to generate a P-chiral bicyclo[4.3.1]phosphate containing ample steric and stereoelectronic differentiation for investigating chemo-, regio-, and stereoselective transformations. Overall, the method reported herein demonstrates a fundamentally new role of phosphates in synthesis and provides differentiated polyol building blocks for use in natural product synthesis." @default.
• W2051902397 created "2016-06-24" @default.
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• W2051902397 date "2005-06-28" @default.
• W2051902397 modified "2023-10-15" @default.
• W2051902397 title "Multivalent Activation in Temporary Phosphate Tethers: A New Tether for Small Molecule Synthesis" @default.
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• W2051902397 doi "https://doi.org/10.1021/ol0512886" @default.
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