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- W205190881 abstract "This chapter focuses on the nature and scope of suitable nonaqueous solvents for inorganic chemistry. There are two considerations that influence the choice of suitable solvent systems: (1) the possibility of dissociating the solute into ions and (2) the possibility of setting up acid–base systems in which the solvent might participate. The application of the acid–base concept has been the dominant theme in the development of nonaqueous solvents in inorganic chemistry. The protonic solvents water and ammonia behave as bases by uniting with a proton. In terms of electron-pair bonding, this requires donation of an electron pair from base to proton. In the Lux–Flood acid–base concept, oxide ions are regarded as the transferable species corresponding to protons in the Lowry–Bronsted scheme. Experimentally, the studies in a nonaqueous solvent require the preparation and purification of the solvent, the means of manipulation, and the methods for the observation of phenomena in it. The means of manipulation depend upon physical properties such as the melting point to boiling point temperature range." @default.
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- W205190881 date "1965-01-01" @default.
- W205190881 modified "2023-09-27" @default.
- W205190881 title "THE NATURE AND SCOPE OF INORGANIC NON-AQUEOUS SOLVENTS" @default.
- W205190881 doi "https://doi.org/10.1016/b978-0-08-011335-7.50005-5" @default.
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