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- W2051912135 abstract "The use of pendant pyrazole groups to induce double cyclopalladation of 2-phenylpyrimidines has been investigated 4,6-Bis(pyrazol-1-yl)-2-phenylpyrimidine undergoes monocyclopalladation only, whilst 4-methyl-2-phenyl-6-(pyrazol-1-ylmethyl)pyrimidine reacts preferentially to give the cyclopalladated regioisomer in which the ligand exhibits tridentate coordination. 4,6-Bis(pyrazol-1-ylmethyl)-2-phenylpyrimidine gives a mixture of singly and doubly cyclopalladated products." @default.
- W2051912135 created "2016-06-24" @default.
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- W2051912135 date "1990-10-01" @default.
- W2051912135 modified "2023-10-16" @default.
- W2051912135 title "Cyclometallated compounds VI. Cyclopalladation of 2-phenylpyrimidines with pendant pyrazole donors" @default.
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- W2051912135 doi "https://doi.org/10.1016/0022-328x(90)85300-n" @default.
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