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• W2051915770 startingPage "3793" @default.
• W2051915770 abstract "Nucleophilic substitution of the cp (η-C5H5) ligand of [Cu(cp)(PPh3)] with LiL (L = 1,3-benzoxazoline-2-thionate) gave the heterobimetallic complex [(Ph3P)2CuL2Li(thf)2]·thf 1(thf = tetrahydrofuran), the ligand-transfer reaction of which with CuCl2 generated the tetrameric cage complex [{CuL(PPh3)}4]2. The crystal structures of these complexes revealed that the association of the metal centres occurs by a variety of ligand co-ordination modes (µ-S, N; N, µ-S; µ3-S). Electrochemical measurements have been used to probe the nature of the species present in solution." @default.
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• W2051915770 date "1996-01-01" @default.
• W2051915770 modified "2023-09-23" @default.
• W2051915770 title "Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [Ph₃P)₂CuL₂Li(thf)₂]·thf and tetrameric [{CuL(PPh₃)}₄](L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran)" @default.
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• W2051915770 doi "https://doi.org/10.1039/dt9960003793" @default.
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