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- W2052001937 abstract "A transition metal-containing Zintl phase, Sr2MnSb2, was prepared from a stoichiometric combination reaction of the elements in Sn flux, and its structure was determined by single-crystal X-ray diffraction methods. The compound crystallizes in the orthorhombic space group Pnma with a = 15.936(3) Å, b = 14.498(3) Å, c = 8.2646(17) Å, and Z = 12. The structure of Sr2MnSb2 is composed of corrugated layers of corner- and edge-shared MnSb4 tetrahedra. The basic building unit of the layer is a [Mn3Sb6]12- cluster composed of three edge-shared MnSb4 tetrahedra. These trinuclear clusters share four Sb vertexes to form a layer with cavities. Sr2+ cations are located at the inter- and intralayer space. Magnetic susceptibility measurements indicate an effective magnetic moment of 4.85 μB, a value smaller than what would be expected from Mn2+ ions." @default.
- W2052001937 created "2016-06-24" @default.
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- W2052001937 date "2005-06-09" @default.
- W2052001937 modified "2023-10-10" @default.
- W2052001937 title "Sr<sub>2</sub>MnSb<sub>2</sub>: A New Ternary Transition Metal Zintl Phase" @default.
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- W2052001937 doi "https://doi.org/10.1021/ic048252e" @default.
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