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- W2052012648 abstract "Products from the irradiation of ten pure perfluoroalkanes at 25°C by 50 to 150 Mrads of γ-rays have been analyzed by gas-liquid chromatography. The numbers of molecules that disappeared per 100 eV absorbed were found to be: ${rm CF}_{4}(1.1), {rm C}_{2}{rm F}_{6}(4.0), {rm C}_{3}{rm F}_{8}(3.7), ntext{-}{rm C}_{4}{rm F}_{10}(3.7), itext{-}{rm C}_{4}{rm F}_{10}(3.3), ntext{-}{rm C}_{5}{rm F}_{12}(3.1), ntext{-}{rm C}_{6}{rm F}_{14}(2.9), 2text{-}{rm CF}_{3}{rm C}_{5}{rm F}_{11}(2.7), 3text{-}{rm CF}_{3}{rm C}_{5}{rm F}_{11},(2.6)$ and $2,3text{-}({rm CF}_{3})_{2}text{-}{rm C}_{4}{rm F}_{8}(5.0)$ . The preponderance of branched product molecules containing CF3 groups indicates that C-F bonds at secondary and tertiary carbon are more susceptible to radiation damage than those at CF3 groups." @default.
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- W2052012648 date "1968-02-01" @default.
- W2052012648 modified "2023-09-24" @default.
- W2052012648 title "Perfluoroalkanes in Ionizing Radiation" @default.
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- W2052012648 doi "https://doi.org/10.2307/3572479" @default.
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