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- W2052014786 abstract "Abstract A common ionic liquid (IL), 1‐butyl‐3‐methylimidazolium tetrafluoroborate (bmimBF 4 ), is used as polar solvent to induce the formation of a reverse bmimBF 4 ‐in‐toluene IL microemulsion with the aid of the nonionic surfactant Triton X‐100. The swelling process of the microemulsion droplets by increasing bmimBF 4 content is detected by dynamic light scattering (DLS), conductivity, UV/Vis spectroscopy, and freeze‐fracture transmission electron microscopy (FF–TEM). The results show that the microemulsion droplets initially formed are enlarged by the addition of bmimBF 4 . However, successive addition of bmimBF 4 lead to the appearance of large‐sized microemulsion droplet clusters (200–400 nm). NMR spectroscopic analysis reveal that the special structures and properties of bmimBF 4 and Triton X‐100 together with the polar nature of toluene contribute to the formation of such self‐assemblies. These unique self‐assembled structures of IL‐based microemulsion droplet clusters may have some unusual and unique properties with a number of interesting possibilities for potential applications." @default.
- W2052014786 created "2016-06-24" @default.
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- W2052014786 date "2008-07-25" @default.
- W2052014786 modified "2023-10-12" @default.
- W2052014786 title "Nanodroplet Cluster Formation in Ionic Liquid Microemulsions" @default.
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- W2052014786 doi "https://doi.org/10.1002/cphc.200800157" @default.
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