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- W2052033963 abstract "A detailed hydrochemical study at two undisturbed Ordovician massive sulphide (Zn–Pb) deposits (Restigouche and Halfmile Lake deposits, Bathurst Mining Camp, New Brunswick) was initiated to elucidate the processes controlling the oxidation and dissolution of sulphide minerals, the subsequent dispersion of metals in ground and surface waters, and the precipitation of secondary minerals. Groundwater hydrogeochemical signatures are different for the two deposits. Elements that form sulphide minerals in the deposits correlate positively in surface waters and increase with proximity to the Restigouche deposit, whereas metal contents for Halfmile Lake surface waters are lower, though still typically higher than background levels. Variations in the composition of ground and surface waters draining the two deposits reflect in part differences in the depth and geometry of the massive sulphides and host lithologies. The Halfmile Lake deposit is deeper, more steeply dipping, and overturned compared to the shallower Restigouche deposit. Groundwaters at the Halfmile Lake deposit up to 760 m below surface are low-TDS (<250 mg l−1), Ca–HCO3 to Na–HCO3 waters with oxygen and hydrogen isotopic compositions identical to surface waters. Groundwater REE patterns are flat to LREE-enriched and are similar to host lithologies, unlike the surface waters which are LREE-depleted compared to shale. The Restigouche groundwaters range up to 21,000 mg l−1 TDS (Na–Cl waters) and display heavier oxygen and hydrogen isotopic compositions than local surface waters. Variations in groundwater composition require that the two deposits have different hydrologies which influence the natural oxidation of the massive sulphides and thus the environmental hydrochemical signature." @default.
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- W2052033963 date "1998-11-01" @default.
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- W2052033963 title "Hydrogeochemical, isotopic, and rare earth element evidence for contrasting water–rock interactions at two undisturbed Zn–Pb massive sulphide deposits, Bathurst Mining Camp, N.B., Canada" @default.
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- W2052033963 doi "https://doi.org/10.1016/s0375-6742(98)00036-3" @default.
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