Matches in SemOpenAlex for { <https://semopenalex.org/work/W2052034295> ?p ?o ?g. }
- W2052034295 endingPage "14304" @default.
- W2052034295 startingPage "14292" @default.
- W2052034295 abstract "Abstract Herein, we report the synthesis of boroles that are linked by a conjugated phenylene spacer. The characterization of these compounds was completed by NMR and UV/Vis spectroscopy, as well as X‐ray crystal diffraction. Furthermore, the coordination behavior of these oligoboroles towards five electronically and sterically disparate pyridine derivatives was studied and revealed fundamental differences in the properties of the resulting adducts. The experimental results were supported by density functional theory (DFT) calculations that showed a charge‐transfer effect upon formation of the pyridine‐4‐carbonitrile adduct. By chemical reduction of a tris(borolyl)‐substituted benzene derivative, a hexaanion was isolated as a result of a two‐electron reduction of each borolyl moiety. The interaction of the borolyl units through the aryl spacer, and the possible increase of the Lewis acidity due to the conjugation of the borolyl moieties, were investigated by base transfer reactions." @default.
- W2052034295 created "2016-06-24" @default.
- W2052034295 creator A5003548029 @default.
- W2052034295 creator A5008446536 @default.
- W2052034295 creator A5014559920 @default.
- W2052034295 creator A5037065857 @default.
- W2052034295 creator A5038029240 @default.
- W2052034295 creator A5041690037 @default.
- W2052034295 creator A5047296162 @default.
- W2052034295 creator A5056569207 @default.
- W2052034295 creator A5078529647 @default.
- W2052034295 creator A5084536262 @default.
- W2052034295 date "2012-09-27" @default.
- W2052034295 modified "2023-10-18" @default.
- W2052034295 title "Oligo(borolyl)benzenes-Synthesis and Properties" @default.
- W2052034295 cites W116545228 @default.
- W2052034295 cites W1553330920 @default.
- W2052034295 cites W1966694815 @default.
- W2052034295 cites W1970893324 @default.
- W2052034295 cites W1973307410 @default.
- W2052034295 cites W1973368088 @default.
- W2052034295 cites W1974066782 @default.
- W2052034295 cites W1978003040 @default.
- W2052034295 cites W1981600895 @default.
- W2052034295 cites W1982106002 @default.
- W2052034295 cites W1982757943 @default.
- W2052034295 cites W1988373046 @default.
- W2052034295 cites W1993392258 @default.
- W2052034295 cites W1999233801 @default.
- W2052034295 cites W2001056479 @default.
- W2052034295 cites W2001108768 @default.
- W2052034295 cites W2008192551 @default.
- W2052034295 cites W2009195167 @default.
- W2052034295 cites W2014705651 @default.
- W2052034295 cites W2017244637 @default.
- W2052034295 cites W2017338793 @default.
- W2052034295 cites W2017580294 @default.
- W2052034295 cites W2019265638 @default.
- W2052034295 cites W2019512570 @default.
- W2052034295 cites W2019751627 @default.
- W2052034295 cites W2022395735 @default.
- W2052034295 cites W2033096521 @default.
- W2052034295 cites W2044987532 @default.
- W2052034295 cites W2060214870 @default.
- W2052034295 cites W2063715453 @default.
- W2052034295 cites W2065742318 @default.
- W2052034295 cites W2066916547 @default.
- W2052034295 cites W2068052889 @default.
- W2052034295 cites W2070263332 @default.
- W2052034295 cites W2072491805 @default.
- W2052034295 cites W2075888866 @default.
- W2052034295 cites W2076139409 @default.
- W2052034295 cites W2079931274 @default.
- W2052034295 cites W2080707098 @default.
- W2052034295 cites W2087823838 @default.
- W2052034295 cites W2091183714 @default.
- W2052034295 cites W2095193265 @default.
- W2052034295 cites W2095729335 @default.
- W2052034295 cites W2099388707 @default.
- W2052034295 cites W2102890851 @default.
- W2052034295 cites W2122746064 @default.
- W2052034295 cites W2131580200 @default.
- W2052034295 cites W2133300466 @default.
- W2052034295 cites W2137893587 @default.
- W2052034295 cites W2138457465 @default.
- W2052034295 cites W2140421632 @default.
- W2052034295 cites W2141072312 @default.
- W2052034295 cites W2142897906 @default.
- W2052034295 cites W2146348249 @default.
- W2052034295 cites W2154752845 @default.
- W2052034295 cites W2159408069 @default.
- W2052034295 cites W2166205344 @default.
- W2052034295 cites W2326647777 @default.
- W2052034295 cites W2330499370 @default.
- W2052034295 cites W2335477119 @default.
- W2052034295 cites W2949604808 @default.
- W2052034295 cites W2950394030 @default.
- W2052034295 cites W4210454826 @default.
- W2052034295 cites W4231129288 @default.
- W2052034295 cites W4232283759 @default.
- W2052034295 cites W4232719593 @default.
- W2052034295 doi "https://doi.org/10.1002/chem.201202345" @default.
- W2052034295 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23019113" @default.
- W2052034295 hasPublicationYear "2012" @default.
- W2052034295 type Work @default.
- W2052034295 sameAs 2052034295 @default.
- W2052034295 citedByCount "32" @default.
- W2052034295 countsByYear W20520342952013 @default.
- W2052034295 countsByYear W20520342952014 @default.
- W2052034295 countsByYear W20520342952015 @default.
- W2052034295 countsByYear W20520342952018 @default.
- W2052034295 countsByYear W20520342952019 @default.
- W2052034295 countsByYear W20520342952020 @default.
- W2052034295 countsByYear W20520342952021 @default.
- W2052034295 countsByYear W20520342952022 @default.
- W2052034295 countsByYear W20520342952023 @default.
- W2052034295 crossrefType "journal-article" @default.
- W2052034295 hasAuthorship W2052034295A5003548029 @default.