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• W2052039312 endingPage "14112" @default.
• W2052039312 startingPage "14103" @default.
• W2052039312 abstract "By using MO calculations based on DFT, absorption, and fluorescence spectroscopy, we have comprehensively studied the low-lying excited singlet states of alpha,omega-diphenylpolyynes (DPY) having 1-6 triple bonds. The a(g) vibrational modes of the C(triple bond)C stretching and of the phenyl ring motion were observed in the fluorescence spectra of diphenylacetylene and 1,4-diphenylbutadiyne. On the other hand, in the fluorescence spectra of the long DPY with the triple-bond number (N) more than two, the phenyl ring motion with a(g) symmetry disappeared and the b(1g) modes of the phenyl ring twisting (approximately 400 cm(-1)) and of the C-H bending (approximately 900 cm(-1)) were detected. The observed fluorescent states of DPY with N < or = 2 and N > or = 3 are assigned to the 1(1)B(1u) (pi(x)pi(x*)) and 1(1)A(u) (pi(x)pi(y*) and/or pi(y)pi(x*)) states, respectively, based on the vibronic structures, the relatively short lifetimes, and the solvatochromic shifts of the fluorescence spectra. Not only the allowed transition of 1(1)B(1u) <-- S(0) but also the forbidden transition of 1(1)A(u) <-- S(0) was detected in the fluorescence excitation spectra of the long DPY with N > or = 3. The low-lying excited state with A(u) symmetry is characteristic in polyyne, which does not exist in polyene. The oscillator strength (f) of the first absorption band in DPY decreases with an increase in N, which is the opposite behavior of the all-trans-alpha,omega-diphenylpolyenes. The N-dependence of the f value is understood by the configuration interaction between the 1(1)B(1u) and 2(1)B(1u) (pi(y)pi(y*)) states, which is consistent with the reduction of the nonlinear optical response of polyyne." @default.
• W2052039312 created "2016-06-24" @default.
• W2052039312 creator A5004446959 @default.
• W2052039312 creator A5043314180 @default.
• W2052039312 creator A5052258589 @default.
• W2052039312 creator A5067944634 @default.
• W2052039312 date "2003-10-23" @default.
• W2052039312 modified "2023-09-24" @default.
• W2052039312 title "Symmetry Switching of the Fluorescent Excited State in α,ω-Diphenylpolyynes" @default.
• W2052039312 cites W1675253846 @default.
• W2052039312 cites W1963526333 @default.
• W2052039312 cites W1963596441 @default.
• W2052039312 cites W1964398752 @default.
• W2052039312 cites W1964637951 @default.
• W2052039312 cites W1967453484 @default.
• W2052039312 cites W1968577448 @default.
• W2052039312 cites W1969016702 @default.
• W2052039312 cites W1969823217 @default.
• W2052039312 cites W1970721044 @default.
• W2052039312 cites W1975002191 @default.
• W2052039312 cites W1977262754 @default.
• W2052039312 cites W1977712035 @default.
• W2052039312 cites W1977731999 @default.
• W2052039312 cites W1984900895 @default.
• W2052039312 cites W1985449174 @default.
• W2052039312 cites W1987089941 @default.
• W2052039312 cites W1989384815 @default.
• W2052039312 cites W1993704155 @default.
• W2052039312 cites W1995815017 @default.
• W2052039312 cites W1996325772 @default.
• W2052039312 cites W1997907471 @default.
• W2052039312 cites W2001452808 @default.
• W2052039312 cites W2005194426 @default.
• W2052039312 cites W2006711141 @default.
• W2052039312 cites W2011527021 @default.
• W2052039312 cites W2012904852 @default.
• W2052039312 cites W2014577148 @default.
• W2052039312 cites W2014632695 @default.
• W2052039312 cites W2016187105 @default.
• W2052039312 cites W2019041579 @default.
• W2052039312 cites W2019201607 @default.
• W2052039312 cites W2023873504 @default.
• W2052039312 cites W2023906389 @default.
• W2052039312 cites W2024037065 @default.
• W2052039312 cites W2024990576 @default.
• W2052039312 cites W2027467909 @default.
• W2052039312 cites W2035194469 @default.
• W2052039312 cites W2039756777 @default.
• W2052039312 cites W2040435905 @default.
• W2052039312 cites W2045887879 @default.
• W2052039312 cites W2046414393 @default.
• W2052039312 cites W2047131583 @default.
• W2052039312 cites W2047187990 @default.
• W2052039312 cites W2047805734 @default.
• W2052039312 cites W2048616482 @default.
• W2052039312 cites W2048974201 @default.
• W2052039312 cites W2055459945 @default.
• W2052039312 cites W2055899737 @default.
• W2052039312 cites W2057997031 @default.
• W2052039312 cites W2058787695 @default.
• W2052039312 cites W2058842466 @default.
• W2052039312 cites W2060974628 @default.
• W2052039312 cites W2063150646 @default.
• W2052039312 cites W2063841912 @default.
• W2052039312 cites W2070690375 @default.
• W2052039312 cites W2073006389 @default.
• W2052039312 cites W2077072974 @default.
• W2052039312 cites W2082425547 @default.
• W2052039312 cites W2083730521 @default.
• W2052039312 cites W2084669769 @default.
• W2052039312 cites W2084762724 @default.
• W2052039312 cites W2085720644 @default.
• W2052039312 cites W2086441858 @default.
• W2052039312 cites W2101816844 @default.
• W2052039312 cites W2116664075 @default.
• W2052039312 cites W2118379785 @default.
• W2052039312 cites W2154877434 @default.
• W2052039312 cites W2171057852 @default.
• W2052039312 cites W2346964781 @default.
• W2052039312 cites W28758994 @default.
• W2052039312 cites W2951611320 @default.
• W2052039312 cites W3191190262 @default.
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• W2052039312 doi "https://doi.org/10.1021/ja035173d" @default.
• W2052039312 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14611247" @default.
• W2052039312 hasPublicationYear "2003" @default.
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