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- W2052053760 abstract "CCl3 has been stabilized both by the reaction of lithium atoms with CCl4 in an argon matrix at 20°K and by the vacuum-ultraviolet photolysis of HCCl3 or of DCCl3 in an argon or a nitrogen matrix at 14°K. The analogous techniques have been found to lead to the stabilization of CBr3. The product spectra obtained in the lithium-atom experiments are considerably simpler than those obtained in the previous studies of the reaction of lithium atoms with matrix-isolated CX4. In the vacuum-ultraviolet photolysis experiments, DCCl2, HCBr2, and CBr2 have also been observed. The absorption frequencies and contours obtained for ν3 of CCl3 and of CBr3 are independent of the method used to produce these species, suggesting that lithium atoms and their reaction products do not appreciably perturb the degenerate stretching mode of either CCl3 or CBr3. Despite yields of these species comparable to those previously reported, absorptions at 674 and at 582 cm−1, previously attributed to ν1 of CCl3 and CBr3, respectively, are completely missing from the present experiments. No other absorption attributable to ν1 of either species has been detected. It is concluded that a pyramidal (C3υ) structure for CCl3 and for CBr3 has not been established." @default.
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- W2052053760 date "1970-03-01" @default.
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- W2052053760 title "Matrix-Isolation Studies of the Infrared Spectra of the Free Radicals CCl3 and CBr3" @default.
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- W2052053760 doi "https://doi.org/10.1063/1.1673285" @default.
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