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• W2052129337 abstract "Molecular beam mass spectrometric work on the lower boron hydrides is reported. Borane, BH3, and tetraborane (8), B4H8, were formed by reactions involving loss of BH3, CO, and, in the latter case, H2 from the appropriate molecules. This ensemble of reactions permitted unambiguous identification of each species. A route to B3H7 from B3H7PX3 is proposed. Investigation of the “stable” and “unstable” boranes and isotopically labelled molecules permits correlations of the mass spectra, determination of a structure ((B4H9)2), and identification of fragmentation pathways. Steady state pyrolysis in the ion source is particularly insidious. Because of it, previous appearance potential and theoretical fragmentation studies of e. g., B4H10 are virtually meaningless." @default.
• W2052129337 created "2016-06-24" @default.
• W2052129337 creator A5036878925 @default.
• W2052129337 date "2010-09-02" @default.
• W2052129337 modified "2023-10-14" @default.
• W2052129337 title "Reactive intermediates and molecular beam mass spectra of the boranes [1]" @default.
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• W2052129337 doi "https://doi.org/10.1002/bscb.19720810107" @default.
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