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- W2052132851 endingPage "1972" @default.
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- W2052132851 abstract "The synthesis of 4-hydroxyestrone and 4-hydroxyestradiol from estr-4-ene-3,17-dione through the 4,5-epoxyestra-3,17-diones is described. Thermolysis of 4-chloro-4,5-epoxyestra-3,17-diones also gives 4-hydroxyestrone, but in lower yield, together with 4-hydroxyestra-4,6-diene-3,17-dione and the B ring aromatic product, estra-5,7,9-triene-4,17-dione. Structures have been established by NMR methods except for the structure of 4β-chloro-4,5-epoxy-5α-estra-3,17-dione which has been determined by X-ray crystallographic analysis." @default.
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- W2052132851 date "1998-01-01" @default.
- W2052132851 modified "2023-10-18" @default.
- W2052132851 title "Synthesis of 4-hydroxyestrogens from steroid 4,5-epoxides: thermal rearrangement of 4-chloro-4,5-epoxides" @default.
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- W2052132851 doi "https://doi.org/10.1039/a709186i" @default.
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