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- W2052150088 abstract "Abstract Interaction of trans-[Rh(i-Nic)4Cl2]3− anions (i-Nic− – isonicotinate anion) with Cu aq 2 + and Co aq 2 + cations in water has afforded complex salts Co3[Rh(i-Nic)4Cl2]2·17H2O (1) and Cu3[Rh(i-Nic)4Cl2]2·14H2O (2). Oligonuclear character of 1 and 2 has been established. A coordination polymer Cu5[Rh(i-Nic)4Cl2]2(i-Nic)2(OH)2·2H2O (3) has been crystallized by hydrothermal treatment of 2 at 160 °C, and its structure was determined by X-ray structural analysis. EPR data for the complexes has been collected and interpreted. Thermal decomposition of the salts was studied by c-DTA. Bimetallic alloys rhodium–copper and rhodium–cobalt have been obtained as final products of thermal decomposition." @default.
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- W2052150088 date "2012-10-01" @default.
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- W2052150088 title "Bimetallic poly- and oligo-nuclear complexes based on a rhodium(III) metalloligand" @default.
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- W2052150088 doi "https://doi.org/10.1016/j.molstruc.2012.05.068" @default.
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