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- W2052150364 abstract "Abstract The effect of using molybdenum and tungsten trioxides as supports for the medium pressure (1.01 MPa) hydrogenation of carbon monoxide over Group VIII metals (Fe, Ni, Ru, Ph, Pd) has been examined. All metals tested, except iron, show activity enhanced by up to two orders of magnitude when either molybdenum or tungsten trioxide replaces silica as the support. The results suggest that under reaction conditions there is fast spillover/reverse spillover of hydrogen between metal and support. This process allows an increased effective hydrogen concentration to the reactive intermediates and hence causes an enhancement of the rates. The lack of enhancement with the supported iron catalyst is due, we believe, to its inability to facilitate fast hydrogen spillover/reverse spillover." @default.
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- W2052150364 date "1986-01-01" @default.
- W2052150364 modified "2023-09-26" @default.
- W2052150364 title "Carbon monoxide hydrogenation over group VIII metals supported on tungsten and molybdenum trioxides" @default.
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- W2052150364 doi "https://doi.org/10.1016/s0166-9834(00)82928-0" @default.
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